Comment 9 for bug 194241

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ScislaC (scislac) wrote : Re: preferences.xml not a valid XML file, or you dont have read permissions on it. inkscape will run with default settings, new settings will not be saved

This was with a now unsupported version of Inkscape. A newer version (0.46) is available. Given that as well as the lack of follow-up on this issue, this bug will be closed. If you continue to have the same problem with the newer version, please feel free to reopen the bug report.